【Objective】 The aim is to enrich the angiosperm germplasm resources in Shanxi Province, and promote research on biodiversity and forest ecosystems in Zhongtiao area. 【Methods】 photos of Zhongtiao Mountains plant specimens and typical features were collated through specimen identification, data access and expert consultation, according to a large number of field vegetation survey. 【Results】 Five species of angiosperms had not been recorded in Shanxi Province, viz. Rumex acetosella L., Anemone narcissiflora subsp. protracta (Ulbrich) Ziman & Fedoronczuk, Cardamine flexuosa With., Impatiens lushiensis Y. L. Chen, Physalis minima L.. 【Conclusion】 These plants belonged to 5 families and 5 genera, These were newly recorded species of angiosperms from Shanxi Province, The discovery of these new records had enriched the angiosperms germplasm resources and provided the basis for the study on the plant diversity and florogenesis of Shanxi Province.